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Tunstall also performed the song live on The Tonight Show with Jay Leno.
The song was one of the candidates for Hillary Clinton's campaign song for her 2008 presidential campaign.
The song also features at the end of the film Blind Dating, which was released in the same year, starring Chris Pine.
Admiring her strength and accomplishments, she suddenly realised what she wanted to do with her life.
Tunstall explained in an interview that the song was "about the photograph of Patti Smith on the cover of Horses", Commenting on the song's later use in The Devil Wears Prada, Tunstall said: "I didn't realize the lyrics could perfectly fit a chick flick, and it could sound like I was singing about wanting to be a fucking model!
The song is Tunstall's highest charting in the United Kingdom, and spent 26 weeks in the Top 75 Singles.
It won her an Ivor Novello Award in 2006 in the category of Best Song Musically and Lyrically.