He is credited to be the first scientist to suggest that the unstable carbon isotope called radiocarbon or carbon 14 might exist in living matter. Libby and his team of scientists were able to publish a paper summarizing the first detection of radiocarbon in an organic sample. Libby who first measured radiocarbon’s rate of decay and established 5568 years ± 30 years as the half-life. Libby was awarded the Nobel Prize in Chemistry in recognition of his efforts to develop radiocarbon dating.1.American Chemical Society National Historic Chemical Landmarks.
There are three principal techniques used to measure carbon 14 content of any given sample— gas proportional counting, liquid scintillation counting, and accelerator mass spectrometry.
In this method, the carbon 14 content is directly measured relative to the carbon 12 and carbon 13 present. Some inorganic matter, like a shell’s aragonite component, can also be dated as long as the mineral’s formation involved assimilation of carbon 14 in equilibrium with the atmosphere.
The method does not count beta particles but the number of carbon atoms present in the sample and the proportion of the isotopes. Samples that have been radiocarbon dated since the inception of the method include charcoal, wood, twigs, seeds, bones, shells, leather, peat, lake mud, soil, hair, pottery, pollen, wall paintings, corals, blood residues, fabrics, paper or parchment, resins, and water, among others.
Radiocarbon, or carbon 14, is an isotope of the element carbon that is unstable and weakly radioactive. Carbon 14 is continually being formed in the upper atmosphere by the effect of cosmic ray neutrons on nitrogen 14 atoms.
It is rapidly oxidized in air to form carbon dioxide and enters the global carbon cycle.